What is RRCConnectionReject in LTE?

It is the downlink LTE RRC message the network sends when a fresh connection-establishment attempt is not accepted.

What should I inspect first in RRCConnectionReject?

Start with waitTime, then follow the next UE behavior such as idle wait or retry.

What comes after RRCConnectionReject?

The UE usually waits, stays idle, or retries fresh access later.

How is it different from RRCConnectionRelease?

RRCConnectionReject denies setup before connected mode exists. RRCConnectionRelease ends a connected context that already exists.